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Even though she managed to stay confident during her 'Come and Get It' performance, Gomez was hardly as cool meeting Mr. Pitt.
Just one day after her big performance at the MTV Movie Awards, Gomez announces something even "bigger."
Zachary Quinto and Chris Pine tell MTV News it's been difficult keeping 'Star Trek Into Darkness' plot points secret.
MTV News rounds up the host's best moments of the night.
And never have they ever looked so sophisticated!